High-capacity embedded compound A
High-capacity embedded in the compound in the development of lithium ion battery
South lithium Fourth (International) Senior Technology Forum today in Shenzhen Convention and Exhibition Center. The General Assembly, "Power 2009 - Power Battery, 3G high-capacity battery, netbook battery" is the theme of hundreds from across the lithium industry experts, corporate executives attended the forum and how to deal with the financial crisis lithium industry and explore new markets, new opportunities, grasp the development trend of the industry and discuss hot.
The following is the macro Sanyo Dr. Nakamura speech text Record:
Moderator: Mr. Xie Xieyang! Have requested the next company over Sanyo, Dr. Nakamura macro.
Nakamura Wang: Thank you very much for inviting me to participate in this forum, I am very honored to be able to participate in the forum. Today I will tell you about what some of our basic research, research on the two materials, the two studies can be at a higher structural stability of the potential to improve the capacity of anode materials. The first is the anode material of lithium-rich, and the second is obtained through the exchange of sodium layer of the anode material states. (PPT)
First, let me first briefly introduce the background of our study, lithium batteries on the market is basically to do with the lithium cobalt oxide anodes with graphite cathode, which is the question of how to to improve the current system of lithium cobalt oxide The capacity of lithium batteries, or even more than the current capacity. We all know, the capacity of graphite which is close to his capacity, and one way is to find a new cathode materials can give us a higher capacity, such as aluminum cathode. Another is to increase the capacity of the anode, and today I want from the second level is to increase the capacity of anode materials in terms of this problem.
PPT summed up what this energy density, energy density is calculated as the average potential of the product capacity × × actual density, can be charged to a higher potential, in fact, this method is to increase the number of lithium cobalt oxide and other materials or MCL and the capacity to improve his energy density. From this number which we can see his potential as a charge to a higher one way to increase the density of them.
I share with these data obtained using the three main channels of the test battery electrode experiments obtained, in addition to this experimental film of aluminum air battery, it's normal capacity is 600-800 mAh. I'm with you first to introduce lithium-rich anode material, can use this formula to write about, you can use some transition metal parts, this is a very typical formula, often marked with a ICM material, the characteristics of this material is his capacity is relatively high, the time to over 200 mA per gram, can reduce the amount of cobalt, so you can reduce costs. The lithium-rich material can be said that many researchers have been numerous studies, some people in office, this is a reference to the papers, many of the data from this paper. Wei Boshi in the last race could have also participated in the meeting, but also to speak. This is the characteristics of lithium-rich materials, phone, black is the first cycle, the red is the second cycle, the capacity is relatively large, is 270 mA per gram, the initial charge and discharge efficiency is relatively high, this situation The following is about 83%. Another feature we can see that there are very different, that is, in the first cycle and second cycle of the curve being a great difference. The slide in the literature which explains the possible mechanism of charge and discharge, in terms of this capacity for this material comes from traditional methods of oxidation, the oxidation of this lithium-rich material, 4.4V when the oxygen by oxidation, materials which release oxygen, manganese will be captured. After the first discharge, the capacity to connect through this oxidation reduction reaction, that is, for this transition metal redox reactions, this layered manganese oxide by this structural change, we can see has been such a material.
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